| # | Pos. | Player | Date of Birth (Age) | Caps | Goals | Club |
|---|
| 1 | GK | Maksym Koval | 9 December 1992 (age 19) | 0 | 0 |  Dynamo Kyiv |
| 12 | GK | Andriy Pyatov | 28 June 1984 (age 27) | 25 | 0 | Shakhtar Donetsk |
| 23 | GK | Oleksandr Horyainov | 29 June 1975 (age 36) | 1 | 0 | Metalist Kharkiv |
|
| 2 | DF | Yevhen Selin | 9 May 1988 (age 24) | 6 | 1 | Vorskla Poltava |
| 3 | DF | Yevhen Khacheridi | 28 July 1987 (age 24) | 9 | 0 | Dynamo Kyiv |
| 5 | DF | Oleksandr Kucher | 22 October 1982 (age 29) | 28 | 1 | Shakhtar Donetsk |
| 13 | DF | Vyacheslav Shevchuk | 13 May 1979 (age 33) | 20 | 0 | Shakhtar Donetsk |
| 17 | DF | Taras Mykhalyk | 28 October 1983 (age 28) | 26 | 0 | Dynamo Kyiv |
| 20 | DF | Yaroslav Rakitskiy | 3 August 1989 (age 22) | 15 | 3 | Shakhtar Donetsk |
| 21 | DF | Bohdan Butko | 13 January 1991 (age 21) | 8 | 0 | Illichivets Mariupol |
|
| 4 | MF | Anatoliy Tymoshchuk | 30 March 1979 (age 33) | 115 | 4 |  Bayern Munich |
| 6 | MF | Denys Harmash | 19 April 1990 (age 22) | 4 | 0 | Dynamo Kyiv |
| 8 | MF | Oleksandr Aliyev | 3 February 1985 (age 27) | 26 | 6 | Dynamo Kyiv |
| 9 | MF | Oleh Husyev | 25 April 1983 (age 29) | 70 | 10 | Dynamo Kyiv |
| 14 | MF | Ruslan Rotan | 29 October 1981 (age 30) | 56 | 6 | Dnipro Dnipropetrovsk |
| 18 | MF | Serhiy Nazarenko | 16 February 1980 (age 32) | 48 | 12 | Tavriya Simferopol |
| 19 | MF | Yevhen Konoplyanka | 29 September 1989 (age 22) | 17 | 5 | Dnipro Dnipropetrovsk |
|
| 7 | FW | Andriy Shevchenko (captain) | 29 September 1976 (age 35) | 106 | 46 | Dynamo Kyiv |
| 10 | FW | Andriy Voronin | 21 July 1979 (age 32) | 71 | 8 |  Dynamo Moscow |
| 11 | MF | Andriy Yarmolenko | 23 October 1989 (age 22) | 19 | 8 | Dynamo Kyiv |
| 15 | FW | Artem Milevskiy | 12 January 1985 (age 27) | 44 | 8 | Dynamo Kyiv |
| 16 | FW | Yevhen Seleznyov | 20 July 1985 (age 26) | 28 | 5 | Shakhtar Donetsk |
| 22 | FW | Marko Devych | 27 October 1983 (age 28) | 19 | 2 | Shakhtar Donetsk |
